个人简历：
曹昌盛，特聘教授，男，博士生导师。1964年5月生。1999年6月毕业于吉林大学化学系，并获得理学博士学位。2000年02月- 2000年12月: 美国University of Notre Dame化学系 博士后；2001年01月- 2003年08月: 美国Michigan State University化学系 博士后；2003年10月- 2005年10月: 加拿大University of British Columbia化学系 研究员；2005年10月- 2007年03月: 加拿大University of Calgary化学系 研究员；2007年04月- 2008年07月: 加拿大York University化学系 研究员；2008年8月至今在江苏师范大学任教，2008年度江苏省高校“青蓝工程”科技创新团队的团队带头人。2009年江苏省“333工程”第三批第三层次培养对象。主讲《有机化学》、《高等有机化学》和《金属有机化学》等课程。主要从事金属有机化合物的合成及其均相催化研究，目前已经发表SCI学术论文80余篇，被引用超过1000次。
研究领域
1. 金属有机化合物的合成及均相催化的研究工作。包括金属有机化合物催化C-X (X = C, N, O, S, Si, P等)键的形成；
2. CO2活化及参与有机反应的研究；
3. 天然有机小分子及药物中间体的合成；
4.利用化学去油污原理研制治疗2型糖尿病的药物。
主持项目
1. 氮杂环卡宾（NHC）催化二氧化碳参与有机反应的研究(21172188), 国家自然科学基金，2012.01~2015.12；
2. 有机合成方法学(08QLT001), “青蓝工程”科技创新团队, 江苏省教育厅, 2008.12~2012.09;
3. NHC卡宾作用下CO2的化学活性研究, 江苏省“333工程”经费资助, 江苏省人事厅, 2011.01 ~ 2013.12.
代表论文
1. Qianwei Chen, Shufeng Wu, Shuqin Yan, Chengxi Li, Hayrul Abduhulam, Yanhui Shi*,Yanfeng Dang*, Changsheng Cao*Suzuki-Miyaura Cross-Coupling of Sulfoxides, ACS Catalysis, 2020, 10(15), 8168-8176.
2. Yibo Zhao, Liqian Zhang, Xu Li, Yanhui Shi*, Ruru Ding, Mengting Teng, Peng Zhang*, Changsheng Cao*, Peter J. Stang*, Self-assembled ruthenium (II) metallacycles and metallacages with imidazole-based ligandsand their in vitro anticancer activity, PNAS (Proceedings of the National Academy of Sciences of the United States of America), 2019, 116(10), 4090-4098.
3. Qianwei Chen, Fengchen Gao, Huiling Tang, Miao Yao, Qian Zhao, Yanhui Shi*, Yanfeng Dang*, Changsheng Cao*, Sonogashira Cross-Coupling of Aryltrimethylammonium Salts, ACS Catalisis, 2019, 9, 3730−3736.
4. Congmin Mei, Yibo Zhao, Qianwei Chen, Changsheng Cao*, Guangsheng Pang and Yanhui Shi*, Synthesis of oxazolidinones and derivatives through three-component fixation of carbon dioxide, ChemCatChem, 2018, 10(14), 3057-3068.
5. Zhang, Xianqiang Kong, Changsheng Cao*, Guangsheng Pang, Yanhui Shi*, An efficient ternary catalyst ZnBr2/K2CO3/[Bmim]Br for chemical fixation of CO2 into cyclic carbonates at ambient conditions, Journal of CO2 Utilization, 2016, 14, 76–82.
6. Xianqiang Kong, Huizi Zhang, Changsheng Cao, Shengliang Zhou*, Guangsheng Pang, Yanhui Shi*, Synthesis of fluorinated carbazoles via C–H arylation catalyzed by Pd/Cu bimetal system and their antibacterial activities, Bioorganic & Medicinal Chemistry, 2016, 24, 1376–1383.
7. Man Chao, Huizi Zhang, Zhongyu Li, Yibo Zhao, Changsheng Cao*, Guangsheng Pang, Yanhui Shi*, One-pot synthesis of amino-functionalized ethylene carbonates under atmospheric pressure of CO2, Journal of CO2 Utilization, 2016, 16, 412–419.
8. Yunqing Xiao, Xianqiang Kong, Zhicheng Xu, Changsheng Cao*, Guangsheng Pang, Yanhui Shi*, synthesis of quinazoline-2,4(1H,3H)-diones from CO2 catalyzed by N-heterocyclic carbene at atmospheric pressure, RSC Adv., 2015, 5, 5032–5037.
9. Xianqiang Kong, Huizi Zhang, Yunqing Xiao, Changsheng Cao*, Yanhui Shi*, Guangsheng Pang, Effective, transition metal free and selective C–F activation under mild conditions, RSC Adv., 2015, 5, 7035–7048.
10. Zhicheng Xu, Yunqing Xiao, Hong Ding, Changsheng Cao, Haitao Li, Guangsheng Pang, Yanhui Shi*, Palladium / N-Heterocyclic Carbene Catalyzed Mono- and Double-Cyanation of Aryl Halides Using Potassium Ferrocyanide Trihydrate under Aerobic Conditions, Synthesis, 2015, 47(11), 1560-1566.
11. Y. Shi*, I. Sánchez-Molina, C. Cao, T. R. Cook, P. J. Stang*, Synthesis and photophysical studies of self-assembled multicomponent supramolecular coordination prisms bearing porphyrin faces, PNAS (Proceedings of the National Academy of Sciences of the United States of America), 2014, 111(26), 9390–9395.
12. Y. Li, G. Liu, C. Cao*, S. Wang, Y. Li, G. Pang, Y. Shi*, Controlled mono- and double-Heck reaction catalyzed by a dicarbene dipalladium complex, Tetrahedron, 2013, 69, 6241-6250.
13. L. Yang, Y. Li, Q. Chen, Y. Du, C. Cao, G. Pang, Y. Shi*, Sonogashira/hydroarylation sequential reactions: catalyzed by NHCPd complexes, Tetrahedron, 2013, 69(25), 5178-5184.
14. Pan He, Yufeng Du, Gang Liu, Changsheng Cao*, Yanhui Shi*, Juan Zhang, Guangsheng Pang, The regioselective Larock indole synthesis catalyzed by NHC–palladium complexes, RSC Adv., 2013, 3, 18345–18350.
15. Qian Chen, Lanlan Lv, Meng Yu, Yanhui Shi*, Yuling Li, Guangsheng Pang, Changsheng Cao*, Simple, efficient and reusable Pd–NHC catalysts for hydroamination, RSC Adv., 2013, 3, 18359–18366.
16. L. Yang, P. Guan, P. He, Q. Chen, C. Cao*, Y. Peng, Z. Shi, G. Pang, Y. Shi*, Synthesis and characterization of novel chiral NHC–palladium complexes and their application in copperfree Sonogashira reactions, Dalton Trans., 2012, 41(16), 5020-5025.
17. X. Liu, C. Cao*, Y. Li, P. Guan, L. Yang, Y. Shi*, Cycloaddition of CO2 to Epoxides Catalyzed by N-Heterocyclic Carbene (NHC)/ZnBr2 System under Mild Conditions, Synlett, 2012, 23, 1343-1348. Organic Chemistry Portal: Abstracts
18. P. Guan, C. Cao*, Y. Liu, Y. Li, P. He, Q. Chen, G. Liu, Y. Shi*, Efficient nickel/N-heterocyclic carbene catalyzed C–S cross-coupling, Tetrahedron Letters, 2012, 53, 5987–5992.
19. C. Cao*, L. Wang, Z. Cai, L. Zhang, J. Guo, G Pang, Y. Shi*, Palladium Catalyzed α-Ketone Arylation under Mild Condition, Eur. J. Org. Chem., 2011, 1570-1574.
20. C. Cao*, Y. Zhuang, J. Zhao, Y. Peng, X. Li, Z. Shi, G. Pang, Y. Shi*, Binuclear palladium complexes bridged by dicarbene with different lengths and their application in Mizoroki-Heck reaction, Inorg. Chim. Acta, 2010, 363, 3914–3918.
21. C. Cao, T. Wang, B. O. Patrick, J. A. Love, Orthometalation of Tp*Rh(PPh3)2: Implications for Catalytic Reactivity. Organometallics, 2006, 25(5), 1321-1324.
22. C. Cao, L. R. Fraser, J. A. Love, Rhodium-Catalyzed Alkyne Hydrothiolation with Aromatic and Aliphatic Thiols. J. Am. Chem. Soc., 2005, 127(50), 17614-17615.
23. C. Cao, Y.-H. Li, Y. Shi, A. L. Odom, α,β-Unsaturated imines from titanium hydroamination and functionalization by rhodium C-H activation, Chem. Comm., 2004, 17, 2002-2003.
24. C. Cao, S. Dahal, M. Shang, A. M. Beatty, W. Hibbs, C. E. Schulz, W. R. Scheidt, Effect of the sixth axial ligand in CS-ligated iron(II) octaethylporphyrinates: structural and mossbauer studies, Inorg. Chem., 2003, 42, 5202-5210.
25. C. Cao, Y. Shi, A. L. Odom, A titanium-catalyzed 3-component coupling, J. Am. Chem. Soc., 2003, 125, 2880-2881.
26. C. Cao, Y. Shi, A. L. Odom, Intermolecular alkyne hydroamination involving 1, 1-disubstituted hydrazines, Org. Lett., 2002, 4, 2853-2856.
27. C. Cao, J. T. Ciszewski, A. L. Odom, Hydroamintion of alkynes catalyzed by a titanium pyrrolyl complex, Organometallics, 2001, 20, 5011-5013.
授权专利
1. Changsheng Cao, Shengliang Zhou, Yanhui Shi, Fluorine-containing series carbazole compounds useful in treatment of bacterial infection and their preparation, Faming Zhuanli Shenqing, 2016, CN 105272903A 20160127.
2. Changsheng Cao, Yanhui Shi, Huizi Zhang, Xianqiang Kong, Catalyst system for preparing ethylene carbonate derivatives by reaction of carbon dioxide and epoxyethane derivatives under extremely mild conditions, Faming Zhuanli Shenqing, 2015, CN 105126912 A 20151209.
联系方式
Email: chshcao@jsnu.edu.cn
