个人简历:
史延慧,女,1970年7月生,博士,教授。“江苏省高层次创新创业人才计划”引进人才,江苏省教育厅“青蓝工程”中青年学术带头人(2008)和“有机合成方法学”科技创新团队骨干成员(2008)。2000年毕业于吉林大学“无机合成与制备化学国家重点实验室”,获得理学博士学位。2000年6月 - 2008年8月在美国密西根州立大学(Michigan State University),加拿大英属哥伦比亚大学(British Columbia University)等高校从事博士后和教学科研工作。2013-2015年在美国犹他大学(University of Utah)做高级访问学者。2019-2020年在加拿大多伦多大学(University of Toronto)做高级访问学者。2008年8月至今在江苏师范大学化学化工学院任教,主讲现代有机合成(双语)、有机合成与设计(双语)、有机化学(双语)、化学专业英语等课程。被评为2011年本科生毕业论文(设计)优秀指导教师。2015年指导的王光英同学获得“江苏省优秀本科毕业论文三等奖”。主要从事有机合成、金属有机催化、超分子自组装及其抗癌性能等方面的研究。目前已经发表论文80余篇。
研究领域和兴趣
有机合成;金属有机催化;超分子自组装及抗癌性能
主持项目
1. 异双金属NHC卡宾化合物的合成与协同催化研究(21571087), 国家自然科学基金面上项目,2016年01-2019年12;
2. 高性能钯催化剂的开发及其在合成新型绿颜色颜料的应用(14KJA150004),江苏省高校自然科学研究重大项目, 2015年7月-2018年6月;
3. 后过渡金属在氢胺化反应的应用(21071121),国家自然科学基金面上项目,2010年01-2013年12;
4. 研究生有机化学的双语教学及研究,省教育厅,2011-2013
5. 镍卡宾化合物催化C-N键的构造,吉林大学无机合成与制备化学国家重点实验室重点项目, 2009.01-2017.12
6. 新型氢胺化反应催化剂的设计与合成,南京大学配位化学国家重点实验室一般项目,2011.01-2012.12
代表论文
1. Qianwei Chen, Shufeng Wu, Shuqin Yan, Chengxi Li, Hayrul Abduhulam, Yanhui Shi*, Yanfeng Dang*, Changsheng Cao*Suzuki-Miyaura Cross-Coupling of Sulfoxides, ACS Catalysis, 2020, 10, 15, 8168-8176.
2. Yibo Zhao, Liqian Zhang, Xu Li, Yanhui Shi*, Ruru Ding, Mengting Teng, Peng Zhang*, Changsheng Cao*, Peter J. Stang*, Self-assembled ruthenium (II) metallacycles and metallacages with imidazole-based ligandsand their in vitro anticancer activity, Proc. Natl. Acad. Sci. USA, 2019, 116(10), 4090-4098.
3. Qianwei Chen, Fengchen Gao, Huiling Tang, Miao Yao, Qian Zhao, Yanhui Shi*, Yanfeng Dang*, Changsheng Cao*, Sonogashira Cross-Coupling of Aryltrimethylammonium Salts, ACS Catalisis, 2019, 9, 3730−3736.
4. Congmin Mei, Yibo Zhao, Qianwei Chen, Changsheng Cao*, Guangsheng Pang and Yanhui Shi*, Synthesis of oxazolidinones and derivatives through three-component fixation of carbon dioxide, ChemCatChem, 2018, 10(14), 3057-3068.
5. Huizi Zhang, Xianqiang Kong, Changsheng Cao*, Guangsheng Pang, Yanhui Shi*, An efficient ternary catalyst ZnBr2/K2CO3/[Bmim]Br for chemical fixation of CO2 into cyclic carbonates at ambient conditions, Journal of CO2 Utilization, 2016, 14, 76–82.
6. Xianqiang Kong, Huizi Zhang, Changsheng Cao, Shengliang Zhou*, Guangsheng Pang, Yanhui Shi*, Synthesis of fluorinated carbazoles via C–H arylation catalyzed by Pd/Cu bimetal system and their antibacterial activities, Bioorganic & Medicinal Chemistry, 2016, 24, 1376–1383.
7. Man Chao, Huizi Zhang, Zhongyu Li, Yibo Zhao, Changsheng Cao*, Guangsheng Pang, Yanhui Shi*, One-pot synthesis of amino-functionalized ethylene carbonates under atmospheric pressure of CO2, Journal of CO2 Utilization, 2016, 16, 412–419.
8. Yunqing Xiao, Xianqiang Kong, Zhicheng Xu, Changsheng Cao*, Guangsheng Pang, Yanhui Shi*, synthesis of quinazoline-2,4(1H,3H)-diones from CO2 catalyzed by N-heterocyclic carbene at atmospheric pressure, RSC Adv., 2015, 5, 5032–5037.
9. Xianqiang Kong, Huizi Zhang, Yunqing Xiao, Changsheng Cao*, Yanhui Shi*, Guangsheng Pang, Effective, transition metal free and selective C–F activation under mild conditions, RSC Adv., 2015, 5, 7035–7048.
10. Zhicheng Xu, Yunqing Xiao, Hong Ding, Changsheng Cao, Haitao Li, Guangsheng Pang, Yanhui Shi*, Palladium / N-Heterocyclic Carbene Catalyzed Mono- and Double-Cyanation of Aryl Halides Using Potassium Ferrocyanide Trihydrate under Aerobic Conditions, Synthesis, 2015, 47(11), 1560-1566.
11. Yanhui Shi*, Irene Sánchez-Molina, Changsheng Cao, Timothy R. Cook, Peter J. Stang*, Synthesis and photophysical studies of self-assembled multicomponent supramolecular coordination prisms bearing porphyrin faces, Proc. Natl. Acad. Sci. USA, 2014, 111 (26), 9390-9395.
12. Longguang Yang, Pei Guan, Pan He, Qian Chen, Changsheng Cao, Yu Peng, Zhang Shi, Guangsheng Pang, Yanhui Shi*, Synthesis and characterization of novel chiral NHC-palladium complexes and their application in copper-free Sonogashira reactions, Dalton Trans., 2012, 41(16), 5020-5025.
13. Y. Li, Yanhui Shi, A. L. Odom, Titanium Hydrazido and Imido Complexes: Synthesis, Structure, Reactivity, and Relevance to Alkyne Hydroamination, J. Am. Chem. Soc., 2004, 126(6), 1794-1803.
14. Yanhui Shi, W. Chen, K. D. John, R. E. D. Re, J. L. Cohn, G. Xu, J. L. Eglin, A. P. Sattelberger, C. R. Hare, and T. Ren, Diosmium(III) compounds supported by 2-anilinopyridinate and novel alkynyl derivatives, Inorg. Chem., 2005, 44(16), 5719-5725.
15. Yanhui Shi, G. T. Yee, G. Wang, and T. Ren, A new direction in carbon-rich organometallic wires: diruthenium compounds bridged by E-hex-3-ene-1,5-diyn-diyl, J. Am. Chem. Soc., 2004, 126, 10552-105553.
16. Yanhui Shi, Changsheng Cao, Aaron L. Odom, Synthesis and Group 4 complexes of Tris (pyrrolyl -α- methyl)amine, Inorg. Chem., 2004, 43(1), 275-281.
17. Yanhui Shi, C. Hall, J. T. Cisaewski, C.S. Cao and A.L. Odom, Titanium Dipyrrolylmethane Derivatives: Rapid Intermolecular Alkyne hydroamination, Chem. Comm., 2003, 5, 586-587.
18. C. S. Cao, Yanhui Shi, A. L. Odom, A Titanium-Catalyzed 3-component Coupling, J. Am. Chem. Soc., 2003, 125(10), 2880-2881.
联系方式
E-mail:yhshi@jsnu.edu.cn