姓名:董奎勇
系所:化学系
职称:副教授
邮箱:kydong@jsnu.edu.cn
个人简介:
董奎勇,1989年07月生,博士研究生,江苏师范大学讲师。2012 年毕业于皖南医学院获理学学士学位,随后进入苏州大学学习,师从刘峰教授,2015年获得苏州大学医学硕士学位;同年06月进入苏州大学材料与化学化工学部任科研助理职务,合作导师徐新芳教授;2017年09月加入徐新芳教授课题组攻读博士学位,于2021年06月获得苏州大学理学博士学位。2019年10月—2021年05月期间,通过“国家建设高水平大学公派研究生”项目,在美国德克萨斯大学圣安东尼奥分校进行公派交流,合作导师Michael P. Doyle 。2021年10月加入江苏师范大学化学与材料科学学院,目前主要从事不对成环加成反应研究及杂环化合物和生物活性分子的高效合成。近年来发表SCI论文20多篇,主要包括Nature Commun、 Angew. Chem. Int. Ed.、ACS Catal. Org. Lett. Chem. Commun.以及Org. Chem. Front.等。
主要论文:
1. Kuiyong Dong ,* Mengting Liu and Xinfang Xu * Recent Advances in Catalytic Alkyne Transformation via Copper Carbene Intermediates.Molecules 2022, 27, 3088.
2. Kuiyong Dong, Raj Gurung, Xinfang Xu* and Michael P. Doyle* Enantioselective Catalytic Cyclopropanation–Rearrangement Approach to Chiral Spiroketals. Org. Lett. 2021, 23, 3955.
3. Kuiyong Dong, Ahmad Humeidi, Wendell Griffith, Hadi Arman, Xinfang Xu* and Michael P. Doyle* AgI-Catalyzed Reaction of Enol Diazoacetates and Imino Ethers: Synthesis of Highly Functionalized Pyrroles.Angew. Chem. Int. Ed. 2021, 60,13394.
4. Kuiyong Dong, Haifeng Zheng, Yongliang Su, Ahmad Humeidi, Hadi Arman, Xinfang Xu* and Michael P. Doyle* Catalyst-Directed Divergent Catalytic Approaches to Expand Structural and Functional Scaffold Diversity via Metallo-Enolcarbene Intermediates. ACS Catal. 2021, 11, 4712.
5. Kuiyong Dong, Xinfang Xu* and Michael P. Doyle* Copper(I)-catalyzed highly enantioselective [3 + 3]-cycloaddition of γ-alkyl enoldiazoacetates with nitrones. Org. Chem. Front. 2020, 7, 1653.
6. Kuiyong Dong, Xing Fan, Chao Pei, Yang Zheng, Sailan Chang, Ju Cai, Lihua Qiu, Zhi-Xiang Yu *and Xinfang Xu* Transient-axial-chirality controlled asymmetric rhodium-carbene C(sp2)-H functionalization for the synthesis of chiral fluorenes. Nature Communications 2020, 11, 2363.
7. Kuiyong Dong, Kostiantyn O. Marichev, and Michael P. Doyle* Role of Donor−Acceptor Cyclopropenes in Metal Carbene Reactions.Conversion of E Substituted Enoldiazoacetates to Z Substituted Metallo-Enolcarbenes. Organometallics 2019, 38, 4043.
8. Kuiyong Dong, Kostiantyn O. Marichev , Xingfang Xu* and Michael P. Doyle* High Stereocontrol in the Preparation of Silyl-Protected γ-Substituted Enoldiazoacetates. Synlett. 2019, 30, 1457.
9. Kuiyong Dong, Chao Pei, Qian Zeng, Lihua Qiu, Wenhao Hu, Yu Qian and Xinfang Xu* Copper-catalyzed [4+1]-annulation of 2-alkenylindoles with diazoacetates: a facile access to dihydrocyclopenta[b]indoles. Chem. Commun. 2019, 55, 6393.
10. Kuiyong Dong, Chao Pei, Qian Zeng, Hanlin Wei, Michael P. Doyle* and Xinfang Xu* Selective C(sp3)–H Bond Insertion in Carbene/Alkyne Metathesis Reactions. Enantioselective Construction of Dihydroindoles. ACS Catal. 2018, 8, 9543.
11. Kuiyong Dong, Bin Yan, Sailan Chang, Yongjian Chi, Lihua Qiu* and Xinfang Xu* Transition-Metal-Free Fluoroarylation of Diazoacetamides: A Complementary Approach to 3-Fluorooxindoles. J. Org. Chem. 2016, 81, 6887.
12. Kuiyong Dong, Lihua Qiu and Xinfang Xu*Current Organic Chemistry, 2016, 20, 29.
13. Kui-Yong Dong, Hai-Tao Qin, Feng Liu*and Chen Zhu* Oxime-Mediated Oxychlorination and Oxybromination of Unactivated Olefins. Eur. J.Org. Chem. 2015, 1419.
14. Kui-Yong Dong, Hai-Tao Qin, Xing-Xing Bao, Feng Liu* and Chen Zhu* Oxime-Mediated Facile Access to 5-Methylisoxazoles and Applications in the Synthesis of Valdecoxib and Oxacillin.Org. Lett. 2014, 16, 5266.

